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Combined Approaches to Xylose Production from Corn Stover by Dilute Acid Hydrolysis

机译:稀酸水解玉米秸秆生产木糖的综合方法

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摘要

Corn stover is a lignocellulosic biomass, an agricultural by-product, a possible raw material for xylose production. In this study corn stover was hydrolyzed with sulfuric and hydrochloric acid. In the presented work, hydrochloric acid resulted in the highest, 88.8 % xylose yield of theoretical under the conditions of 2 % (w/w) hydrochloric acidconcentration, 40-minute reaction time, 10 % (w/w) dry matter, at 120 °C. Sulfuric acid experiments resulted in 81.9 % xylose yield of theoretical by using 1.5 % (w/w) sulfuric acid, 60-minute reaction time, at 140 °C, 7 % (w/w) dry matter. Acid hydrolysis at lowdry matter content resulted in relatively low sugar concentrations. Hydrolyzate recycling concentrated xylose to three-times, while the recycling does not decrease the xylose yields. It is also shown that the pseudo first-order and biphasic kinetic models can be based on total sugar concentrations.This work is licensed under a Creative Commons Attribution 4.0 International License.
机译:玉米秸秆是木质纤维素生物质,一种农业副产品,可能是生产木糖的原料。在这项研究中,玉米秸秆被硫酸和盐酸水解。在提出的工作中,在120%的盐酸浓度,40分钟的反应时间,10%(w / w)的干物质条件下,盐酸导致理论值的最高木糖产率为88.8%。 ℃。硫酸实验通过使用1.5%(w / w)硫酸,140分钟的反应时间,在140°C下干燥7%(w / w)的干物质,理论上的木糖产率为81.9%。低干物质含量下的酸水解导致糖浓度相对较低。水解产物循环浓缩木糖至三倍,而循环并不会降低木糖产量。还显示出伪一级和双相动力学模型可以基于总糖浓度。这项工作是根据知识共享署名4.0国际许可获得许可的。

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